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Geoffrey S. Sinclair Robert C. M. Claridge Andrew J. Kukor W. Scott Hopkins Derek J. Schipper 《Chemical science》2021,12(6):2304
Non-covalent bonding interactions, such as chalcogen bonding, can have a substantial effect on the electronic and physical properties of conjugated polymers and is largely dependent on the strength of interaction. Functional groups that are traditionally used to instill chalcogen bonding such as alkoxy or fluorine substituents can demand challenging synthetic effort, as well as have drastic effects on the electronics of a π-system. The incorporation of a N-oxide functionality into bithiazole-containing materials, a synthetically simple transformation, has been entirely overlooked until now. A systematic analysis of the effects of N-oxidation on the electronic and physical properties of bithiazole-containing materials has been undertaken. N-Oxidation has been found to affect the electronic band gap through increase of the HOMO and lowering of the LUMO. Furthermore, exceptionally strong intramolecular S–O chalcogen bonding interactions in the bithiazole core contribute to rigidification of the conjugated system. Computational analysis of this system has shown this N-oxide chalcogen bonding interaction to be significantly stronger than other chalcogen bonding interactions commonly exploited in conjugated materials. N-Oxide incorporation into thiazole-containing conjugated materials can have substantial effects on both the electronic and physical properties. A notably strong non-covalent S–O interaction is observed between the N-oxide and neighbouring sulfur. 相似文献
77.
Haines TJ Bionta RM Blewitt G Bratton CB Casper D Claus R Cortez BG Errede S Foster GW Gajewski W Ganezer KS Goldhaber M Jones TW Kielczewska D Kropp WR Learned JG Lehmann E LoSecco JM Matthews J Park HS Price LR Reines F Schultz J Seidel S Shumard E Sinclair D Sobel HW Stone JL Sulak L Svoboda R van der Velde JC Wuest C 《Physical review letters》1986,57(16):1986-1989
78.
Sangster T Spence M Sinclair P Payne R Smith C 《Rapid communications in mass spectrometry : RCM》2004,18(12):1361-1364
Ion suppression is a well-known phenomenon in electrospray ionization (ESI) mass spectrometry. These suppression effects have been shown to adversely affect the accuracy and precision of quantitative bioanalytical methods using ion spray. Such suppression effects have not been as well defined in atmospheric pressure chemical ionization (APCI) and there is some debate whether these effects actually occur in the ionization process using APCI. Here an example is described where clear ion suppression was observed during studies on a model compound and three metabolites using APCI liquid chromatography/tandem mass spectrometry (LC/MS/MS). 相似文献
79.
M. Sanderova K. Sandera V. Stehlik K. Gandera L. Sattler J. E. Mull I. Lorge I. Sorgato F. Pridal A. Conlin C. Smolenski T. Pietrzykowski V. Dejmek F. Stern F. Kryz R. Ofner W. R. Fetzer J. W. Evans W. Z. Hassid M. Nurmia F. W. Zerban W. J. Hughes M. H. Wiley J. N. Taran Mary Scott E. S. West E. Roboz G. Vavrinecz M. Nordlund D. A. Magraw C. W. Sievert F. Massa M. Kminek S. Sanya H. Riehm H. C. S. de Whalley Ö. Fernández M. de Mingo G. Oschmjan M. Kudrjawzewa W. B. Sinclair E. T. Bartholomew K. P. Jácobsohn J. Mayrhofer E. Jekel A. Josz S. Molirískij 《Analytical and bioanalytical chemistry》1937,108(11-12):445-455